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Design of New Water Receptors Based on Oligomeric Complexes of Copper(II) and Nickel(II)

Author: Lampeka Y.D.  

Publisher: Springer Publishing Company

ISSN: 0040-5760

Source: Theoretical and Experimental Chemistry, Vol.38, Iss.5, 2002-09, pp. : 342-346

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Abstract

The interaction of mono- and oligomacromolecular complexes of copper(II) and nickel(II) with water vapor has been studied on a piezoquartz microbalance. It has been established that the effectiveness of adsorption is determined by the nature of the metal ion to a larger extent than the quantity of macrocyclic ligand in the receptor molecule. Oligomacrocyclic complexes of copper(II) are shown to have prospects for use as active coverings of moisture meters working over a wide range of relative humidity.

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