The effect of PbS nanoparticles on the formation of PbSe in aqueous solutions of sodium selenosulfate and lead(II)

Author: Stroyuk A.   Raevskaya A.   Kuchmii S.  

Publisher: Springer Publishing Company

ISSN: 0040-5760

Source: Theoretical and Experimental Chemistry, Vol.42, Iss.6, 2006-11, pp. : 346-351

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Abstract

It was established that PbS nanoparticles significantly increase the rate of formation of lead selenide during the reaction of Pb(NO3)2 and Na2SeSO3 in aqueous solutions of polymers. It was shown that the reaction product consists of PbS/PbSe nanoparticles with a “PbS core-PbSe shell” structure. A correlation was found between the forbidden band widths of the PbS nanoparticles and the PbS/PbSe nanostructures formed during the reaction.