Author： Pastorek R. Trávníček Z. šindelá SRC="/iso-ents/isolat2/rcaron-s.gif" ALT="rcaron" Z. Březina F.
Publisher： Springer Publishing Company
ISSN： 0340-4285
Source： Transition Metal Chemistry, Vol.24, Iss.3, 1999-06, pp. : 304-305
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Abstract
Binuclear NiII dithiocarbamates, with aromatic monothiols as bridging ligands, of composition [Ni(μ-L) (Rdtc)]2 [dtc = S2CN, R = C4H8O (morph), C5H10 (pip), C4H8 (pld); HL = thiophenol, 4-methylthiophenol or 2-thionaphthol] and [Ni(μ-L)(HR1dtc)]2 {R1 = C11H11N2O (aap)} have been prepared and characterized by elemental analyses, i.r. and electron spectroscopy, magnetochemical and conductivity measurements, and thermal analysis. The methods used indicate that the complexes are diamagnetic, complex non-electrolytes with two square-planar NiS4 chromophores.
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