Imide and anhydride bridged organoiron dinuclear homo and hetero dichalcogeno carboxylate complexes [CpFe(CO)2ECO(C6H4)CO]2NH and [CpFe(CO)2ECO(C6H4)CO]2O; E = S, Se

Author： Jibril I.   Abd-Alhadi E.   Hamadah Z.  

Publisher： Springer Publishing Company

ISSN： 0340-4285

Source： Transition Metal Chemistry, Vol.25, Iss.4, 2000-01, pp. : 407-410

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Organoiron thio- and seleno-terephthaloyl chloride complexes CpFe(CO)_2ECO(C_6H_4)COCl (E = S and Se) react with NaOH and NaNH_2 to give quantitative yields of the acid Cp(CO)_2ECO(C_6H_4)CO_2H and the amide CpFe(CO)_2ECO(C_6H_4)CONH_2 respectively. These amide and acid derivatives react with the terephthaloyl chloride complexes to give a new series of imide-bridged [CpFe(CO)_2ECO(C_6H_4)CO]_2NH and anhydride-bridged [CpFe(CO)_2ECO(C_6H_4)CO]_2O organoiron dinuclear homo and hetero dichalcogeno terephthalate complexes. The complexes were characterized by elemental analysis, i.r. and ^1H-n.m.r. spectra.

Related content

Multifunctional iron thiocarboxylate complexes: synthesis, reactivity and structure of CpFe(CO) 2 SCO-3,5-C 6 H 4 (COCl) 2

By El-khateeb Mohammad  

Transition Metal Chemistry, Vol. 34, Iss. 4, 2009-05 ,pp. : 419-424 (6)

Springer Publishing Company

Access to resources Recommend Favorite

Synthesis, characterization and reactivity of iron-olefin complexes of the type [CpFe(CO) 2 ( 2 -CH 2 &unknown;CHR)] + X - (Cp= 5 -C 5 H 5 ; R=CH 3 to n-C 14 H 29 ; X=PF 6 or BF 4 )

By Clayton H.S.   Moss J.R.   Dry M.E.  

Journal of Organometallic Chemistry, Vol. 688, Iss. 1, 2003-12 ,pp. : 181-191 (11)

Elsevier

Access to resources Recommend Favorite

Synthesis of Aryliron Complexes [CpFe(CO)2Ar] by Palladium-Catalyzed Reactions of [CpFe(CO)2I] with Arylzinc, -Boron, or -Indium Reagents

By Yasuda Shigeo   Asada Yoshihiro   Yorimitsu Hideki   Oshima Koichiro  

Materials, Vol. 2, Iss. 3, 2009-08 ,pp. : 978-991 (14)

MDPI

Access to resources Recommend Favorite

Kinetics and mechanism of the photolytic CO-substitutions of cyclopentadienyl(dicarbonyl)iron thiocarboxylate complexes, Cp′Fe(CO)2SCOR (Cp′ = C5H5, ButC5H4,1,3-Bu2tC5H3; R = alkyl, aryl)

By Tawarah K.M.   Jibril I.   Bani-Fwaz M.Z.  

Transition Metal Chemistry, Vol. 25, Iss. 6, 2000-12 ,pp. : 659-663 (5)

Springer Publishing Company

Access to resources Recommend Favorite

Synthesis and structures of cycloalkylidene-bridged biscyclopentadienyl-tetracarbonyldiiron complexes C(CH_2)_n[(  ^5-C_5H_4)Fe(CO)]_2( μ-CO)_2 (n = 4, 5 and 6)

By Xu S.   Zhang J.   Zhu B.   Wang B.   Zhou X.   Weng L.  

Transition Metal Chemistry, Vol. 27, Iss. 1, 2002-02 ,pp. : 58-61 (4)

Springer Publishing Company

Access to resources Recommend Favorite