Reaction of cis ‐Ru(bpy) 2 Cl 2 with 1‐phenyl 5‐(aminophenyl) 9‐(2‐pyridyl) benzimidazole derivatives: crystal structures of N ‐(4‐chlorophenyl) imidazo[1,5a] pyridine and cis ‐[Ru(bpy) 2 (MeCN) 2 ](ClO 4 ) 2

Author： Chattopadhyay Shyamal Kumar  

Publisher： Springer Publishing Company

ISSN： 0340-4285

Source： Transition Metal Chemistry, Vol.29, Iss.1, 2004-02, pp. : 1-6

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Abstract

Reaction of 1‐phenyl 5‐(aminophenyl) 9‐(2‐pyridyl) benzimidazole derivatives (2) with cis‐Ru(bpy)2Cl2 in MeCN results in the formation of N‐(aryl) imidazo[1,5a] pyridine derivatives (4) and cis‐[Ru(bpy)2(MeCN)2]2+ (5). Crystal structures of N‐(4‐chlorophenyl) imidazo[1,5a] pyridine (4b) and cis‐[Ru(bpy)2(MeCN)2](ClO4)2 (5) are also reported.

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