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Titanium-monosubstituted polyoxometalates: relation between homogeneous and heterogeneous Ti-single-site-based catalysis

Author： Kholdeeva Oxana  

Publisher： Springer Publishing Company

ISSN： 1022-5528

Source： Topics in Catalysis, Vol.40, Iss.1-4, 2006-11, pp. : 229-243

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Abstract

The similarity in the catalytic behaviour of titanium-monosubstituted Keggin type polyoxometalates [PTi(L)W11O39]n- (Ti-POMs) and heterogeneous titanium single-site catalysts in selective oxidations with H2O2 is demonstrated. Recent achievements in the application of Ti-POMs as soluble molecular models for studying mechanisms of oxidation catalysis are reviewed.

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