Author： Heller D.
Publisher： Springer Publishing Company
ISSN： 1022-5528
Source： Topics in Catalysis, Vol.5, Iss.1-4, 1998-01, pp. : 159-176
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Abstract
The influence of the temperature on selectivity is described under special consideration of nonlinearities in the corresponding modified Eyring plots. Reasons for the experimentally well-known behavior are discussed. Furthermore, the conditions for nonlinear temperature behavior are quantified and a concept is described which allows the determination of the temperature dependence of a single reaction pathway in a selection process.
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