Author： Cheblal N. Loëte M. Boudon V.
Publisher： Academic Press
ISSN： 0022-2852
Source： Journal of Molecular Spectroscopy, Vol.197, Iss.2, 1999-10, pp. : 222-231
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Abstract
We present a development of the dipole moment and polarizability operators of octahedral molecules, using a tensorial formalism analogous to the one developed for tetrahedral molecules. These operators are involved in the calculation of the intensities of rovibrational transitions as well as in the calculation of the Stark effect. Expressions for the matrix elements are derived. Two simplified models for the study of the Stark effect in such molecules are also proposed and discussed.
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