μ3‐Oxo‐hexa‐μ2‐pivalato‐(pivalic acid‐κO)bis­(pyridine‐κN)trimanganese(III,III,II)

Publisher： John Wiley & Sons Inc

E-ISSN： 1600-5368|62|12|m3439-m3441

ISSN： 1600-5368

Source： Acta Crystallographica Section E, Vol.62, Iss.12, 2006-12, pp. : m3439-m3441

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Abstract

The asymmetric unit of the title compound, [Mn3(C5H9O2)6O(C5H5N)2(C5H10O2)], comprises two independent and similar [MnIII2MnIIO{(CH3)3CCO2}6(py)2(CH3)3CCOOH] (py = pyridine) mol­ecules each with an Mn3(μ3‐O) core. In each mol­ecule, the Mn atoms have octa­hedral geometry with two coordinated pyridines bonded to two MnIII and a terminal pivalic acid coordinated to the MnII atom.

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