Extracting chemical information from single-wavelength X-ray reflectivity data

Author: Salah Fethi   Harzallah Besma   Mérian Thiphaine   Debarnot Dominique   Poncin-Epaillard Fabienne   van der Lee Arie  

Publisher: Edp Sciences

E-ISSN: 1286-0050|62|1|10304-10304

ISSN: 1286-0042

Source: EPJ Applied Physics (The), Vol.62, Iss.1, 2013-04, pp. : 10304-10304

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Abstract

The possibilities for extracting chemical composition-related information from a singlewavelength X-ray reflectometry experiment are investigated. It is shown that the X-ray absorption of certain elements is sufficient to cause a significant effect on the reflectivity curve, which can be in turn exploited to determine its abundance in the thin film. The limitations are discussed using simulated data and the methodology is applied for the determination of the iodine concentration in iodine-treated thin polyaniline films. More generally the method appears to be very sensitive for the non-destructive determination of the weight percentage of metal nanoparticles in thin polymer films.