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Ultrafast OH-stretching frequency shifts of hydrogen-bonded 2-naphthol photoacid-base complexes in solution

Publisher： Edp Sciences

E-ISSN： 2100-014x|41|issue|06007-06007

ISSN： 2100-014x

Source： EPJ Web of Conference, Vol.41, Iss.issue, 2013-03, pp. : 06007-06007

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Abstract

We characterize the transient solvent-dependent OH-stretching frequency shifts of photoacid 2-naphthol hydrogen-bonded with CH₃CN in the S₀- and S₁-states using a combined experimental and theoretical approach, and disentangle specific hydrogen-bonding contributions from nonspecific dielectric response.

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