Ultrafast One-Photon (232 vs 266 nm) Bond-Selective Photochemistry of Bromoiodomethane (CH2BrI) in Solution

Publisher: Edp Sciences

E-ISSN: 2100-014x|41|issue|05012-05012

ISSN: 2100-014x

Source: EPJ Web of Conference, Vol.41, Iss.issue, 2013-03, pp. : 05012-05012

Access to resources Favorite

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Ultrafast broadband transient absorption spectra measured from the deep-ultraviolet to the near-infrared region following single-photon excitation of bromoiodomethane in acetonitrile at different wavelengths manifest chromophore -selective structural rearrangement and carbon-halogen bond dissociation in solution.