Synthesis of Zn(II) Ion-Imprinted Polymeric Adsorbent for Selective Removal of Zinc from Aqueous Solutions

Author: Ozkahraman Benji  

Publisher: Taylor & Francis Ltd

ISSN: 0360-2559

Source: Polymer-Plastics Technology and Engineering, Vol.50, Iss.2, 2011-01, pp. : 216-219

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Abstract

In this study, Zn(II)-imprinted polymer microbeads were synthesized for selective removal of Zn(II) from aqueous solutions. The microbeads were prepared using methacrylic acid and 1,4-vinyl pyrrolidone as functional monomers, zinc(II)acetate as zinc salt, ethylene glycol dimethacyrlate as a cross-linking agent, azo bisisobutyronitrile as an initiator and hydroxyethyl cellulose as surfactant. The non-imprinted polymer was also prepared for comparison, except without use of the Zn(II) salt. To determine the selectivity of Zn(II)-IIP beads, competitive adsorption experiments were investigated. According to the adsorption capacity values of the microbeads, Zn(II)-IIP beads show good selectivity for the target ion.