Synthesis of a Bicyclic Diamine Derived from Kemp's Acid

Author： Schmaderer Harald   Hohenleutner Andreas   Konig Burkhard  

Publisher： Taylor & Francis Ltd

ISSN： 0039-7911

Source： Synthetic Communications, Vol.39, Iss.14, 2009-01, pp. : 2596-2604

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Abstract

A bicyclic diamine with defined and stable conformation in solution was prepared from Kemp's triacid. The efficient four-step synthesis of the Boc-protected diamine requires only a single purification by column chromatography. X-ray analysis and NMR spectroscopy confirm the structure of the diamine in the solid state and in solution.

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