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Ternary (liquid+liquid) equilibria for (acetonitrile+ethanol or 1-propanol+heptane) and (aniline+methanol+cyclohexane)

Author： Nagata I. Tamura K.

Publisher： Academic Press

ISSN： 0021-9614

Source： Journal of Chemical Thermodynamics, Vol.29, Iss.9, 1997-09, pp. : 941-948

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

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Abstract

The (liquid+liquid) equilibria of {x₁CH₃CN+x₂C₂H₅OH+(1-x₁-x₂)C₇H₁₆} and {x₁CH₃CN+x₂CH₃(CH₂)₂OH+(1-x₁-x₂)C₇H₁₆} at the temperature T=313.15 K, and {x₁C₆H₅NH₂+x₂CH₃OH+(1-x₁-x₂)c-C₆H₁₂} at T=298.15 and T=298.15 and T=300.15 K have been measured. At T=298.15 K the last mixture has only one region of immiscibility, while at T=300.15 K the mixture has two separate biphasic regions. The experimental values have been compared with those predicted with the modified UNIQUAC and extended UNIQUAC models having only binary parameters.

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