A new flow calorimeter for the measurement of the isobaric enthapy increment and the isenthalpic Joule–Thomson effect. Results for methane and (methane + ethane)

Author： Day C. Stephan M. Oellrich L.R.

Publisher： Academic Press

ISSN： 0021-9614

Source： Journal of Chemical Thermodynamics, Vol.29, Iss.9, 1997-09, pp. : 949-971

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Abstract

The present paper describes the design of a new adiabatic flow calorimeter which is capable of measuring the integral Joule–Thomson effect an the isobaric enthalpy increment in the gaseous phase. The underlying principles for calorimetric measurements are discussed, and the measuring devices are described. Heat losses were shown to be significantly less then the experimental accuracy. A theoretical maximum error calculation yielded values within the bounds of 0.9 per cent for the isobaric enthalpy increment and 180 mK for the integral Joule–Thomson effect. The direct measurement results are given for pure methane in the temperature range between room temperature and about 580 K at pressures up to 7 MPa, and for {xC₂H₆+(1-x])CH₄} at x=0.11 and x=0.25 for p=7 MPa in the temperature range between 380 K and 480 K. Other properties such as enthalpy residual and molar heat capacity at constant pressure are also derived and correlated. Good agreement was found with available experimental results from the literature and with the prediction made by the accurate Wagner–Setzmann equation of state for methane. Our results confirm the validity of our experimental and evaluation procedures and extend the experimentally investigated temperature range for methane. Further results for binary and ternary mixtures with water will be published in a subsequent paper.