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Isopiestic study of (calcium chloride + water) and (calcium chloride + magnesium chloride + water)atT = 313.15 K

Author： S. J.B. Gilchrist M.A. delgado E.J.

Publisher： Academic Press

ISSN： 0021-9614

Source： Journal of Chemical Thermodynamics, Vol.33, Iss.4, 2001-04, pp. : 405-411

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Abstract

The osmotic coefficients of aqueous calcium chloride solutions were experimentally determined atT = 313.15 K by the isopiestic method. Magnesium chloride served as the isopiestic standard for the calculation of osmotic coefficients. The molality range covered in this study correspond to about 0.1mol ·kg^{- 1}to 3.0mol · kg^{- 1}. In addition, the osmotic coefficients of aqueous mixtures of calcium chloride and magnesium chloride were determined over the range of ionic strength levels of about 0.1mol · kg^{- 1}to 9mol ·kg^{- 1}and at various mole fractions. The results obtained were correlated by the Pitzer equation.

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