Synthesis and Structure of the Copper(II) Nitrate Complex with 1-(3-Methyl-1-phenylpyrazol-5-onylidene-4)-3,3-dimethyl-1,2,3,4-tetrahydroisoquinoline

Author： Sokol V.   Davydov V.   Merkur'eva N.   Sergienko V.   Al-Saleh O.   Shklyaev Yu.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-3284

Source： Russian Journal of Coordination Chemistry, Vol.31, Iss.11, 2005-11, pp. : 780-789

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

The complex [CuL(NO3)2] ⋅ CH3CN(I), where L is 1-(3-methyl-1-phenylpyrazol-5-onylidene-4)-3,3-dimethyl-1,2,3,4-tetrahydroisoquinoline, is synthesized and studied by X-ray diffraction and IR and electronic absorption spectroscopies. Complex I is prepared by the reaction of copper(II) nitrate crystal hydrate with L in acetonitrile. The coordination polyhedron of the Cu atom in I is a distorted (4 + 1) five-vertex polyhedron, and ligand L in the structure acts as N,O-bidentate bridge. The nitrate groups in I perform different structural functions: monodentate-terminal and anisobidentate. Structure I is composed of polymeric chains -L-Cu(NO3)2-L- and solvate acetonitrile molecules arranged between the chains.

Related content

Copper(II) complex with thienyltrifluoroacetylacetone and dimethyl sulfoxide: Synthesis and crystal structure

By Magerramov A.   Alieva R.   Bakhmanova F.   Sulhnejat R.   Chyragov F.   Askerov R.   Potekhin K.  

Russian Journal of Coordination Chemistry, Vol. 37, Iss. 1, 2011-01 ,pp. : 45-47 (3)

MAIK Nauka/Interperiodica

Access to resources Recommend Favorite

Acetato[hydridotris(5‐methyl‐3‐phenylpyrazol‐1‐yl‐κN2)borato]copper(II)

By  

Acta Crystallographica Section E, Vol. 62, Iss. 9, 2006-09 ,pp. : m2016-m2017 (NaN)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Dichloro­[tris­(3‐methyl‐5‐phenyl­pyrazol‐1‐yl)methane]copper(II) acetonitrile hemisolvate

By  

Acta Crystallographica Section E, Vol. 63, Iss. 3, 2007-03 ,pp. : m685-m686 (NaN)

John Wiley & Sons Inc

Access to resources Recommend Favorite

The Unexpected Synthesis, Crystal Structure, and Thermal Stability of a Copper(II) Complex Derived from 2-[(2-Phenylaminoethylimino)methyl]benzoic Acid

By Qian Shao-Song   Xian Dong-Mei   Ma Yu-Ping   You Zhong-Lu   Zhu Hai-Liang  

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 43, Iss. 10, 2013-11 ,pp. : 1406-1410 (5)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Synthesis, Characterization, and Crystal Structure of a Novel Copper(II) Complex Derived from 2,4-Dibromo-6-[(2-isopropylaminoethylimino)methyl]phenol

By Zhao Xiao-Fan  

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 38, Iss. 10, 2008-12 ,pp. : 774-777 (4)

Taylor & Francis Ltd

Access to resources Recommend Favorite