Synthesis and Crystal Structure of a New Coordination Polymer Constructed From Rigid Tetracarboxylate and N-Donor Ligands

Author： Jun Wang   Lu Lu   Wei-Ping Wu   Bin Xie   Jian-Shen Feng  

Publisher： Taylor & Francis Ltd

ISSN： 1553-3174

Source： Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol.42, Iss.9, 2012-10, pp. : 1217-1221

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Abstract

A new metal-organic framework, [Mn2(L)(4,4-bipy)2(H2O)3]n (1) (H4L = 4,4′-diazenediyldiphthalic acid and 4,4′-bipy = 4,4′-bipyridine), has been synthesized through the hydrothermal method and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic, space group Cc with a = 23.406 (10) Å, b = 16.651(8) Å, c = 10.363 (5) Å, β = 103.437(9)°. The complex exhibits interesting 2D (6,4)-connected framework with (36,44.65)(42,84) topology. The motif is further extended into 3D supramolecular architecture via hydrogen bonding interactions.

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