Publisher： John Wiley & Sons Inc
E-ISSN： 1600-5368|63|12|m3116-m3116
ISSN： 1600-5368
Source： Acta Crystallographica Section E, Vol.63, Iss.12, 2007-12, pp. : m3116-m3116
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Abstract
In the title compound, [MnCl2(C16H15N5)(CH4O)], the manganese(II) cation is six‐coordinate, forming a distorted octahedral configuration with bis(1H‐benzimidazol‐2‐ylmethyl)amine (IDB) serving as a neutral tridentate chelating ligand. Two imine and one amine N atoms from IDB and one Cl anion form the equatorial plane. The two axial positions are occupied by the methanol O atom and the other Cl anion. By a combination of two N–H...Cl and one O—H...Cl hydrogen bonds, molecules are linked into a three‐dimensional network which is strengthened by weak C—H...π and π–π interactions [interplanar spacing = 3.343 (1) Å, ring‐centroid separation = 3.728 (3) Å, corresponding to a ring offset of 1.650 (1) Å].
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