Synthesis, Structures, and Properties of {(BDMLP)2[Pb2I8]} and {(MLDE)[PbI3]} Induced by N-Containing Organic Cation Templates

Author： Wang Chaohai   Li Si   Wu Huanhuan   Shen Lixia   Li Xinghui   Niu Yunyin  

Publisher： Taylor & Francis Ltd

E-ISSN： 1553-3182|45|10|1596-1601

ISSN： 1553-3174

Source： Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol.45, Iss.10, 2015-10, pp. : 1596-1601

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Abstract

Two new cation-templated complexes, (BDMLP)2[Pb2I8]} (1) and {(MLDE)[PbI3]}n (2) [BDMLP = 1,3-bis(dimethylimidazole) propane; MLDE = methylimidazole ethane] have been synthesized via the self-assembly reaction in solution. Single-crystal X-ray diffraction analysis shows compound 1 is a dimer and 2 is a 1D chain. Electrostatic interactions between the organic counteranions and inorganic moieties are present and do the contribution to the crystal packing. These compounds have been further characterized by IR, fluorescence spectrophotometer, and thermostability properties.

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